论文题目 | Quantitative redox measurements for hydrothermal experiments conducted in cold-seal pressure vessels |
论文题目(英文) | Quantitative redox measurements for hydrothermal experiments conducted in cold-seal pressure vessels |
作者 | Fang, Jing(1,2);周義明(3);Audetat, Andreas(1);Zhang, Lipeng(2,4) |
发表年度 | 2024-09-20 |
卷 | 663 |
期 | |
页码 | 9 |
期刊名称 | CHEMICAL GEOLOGY |
摘要 |
The cold-seal pressure vessel (CSPV) is a commonly-used apparatus for hydrothermal experiments performed at crustal temperature (T)-pressure (P) conditions. The redox states of the samples in CSPV hydrothermal experiments are normally controlled by the pressure medium, by using oxygen buffers, or with the Shaw membrane technique. Although these techniques have been widely used, the actual redox states of the samples are not necessarily the expected values and need to be quantitatively measured. In this study, by using CoPd, NiPd, and (NiMn)O redox sensors, quantitative redox measurements have been conducted in H2O-pressurized Ni-superalloy (Inconel 713 LC) CSPVs at 700-800 degrees C and 200 MPa. Oxygen fugacities (fO2) of the H2O pressure medium in three CSPVs used in this study were measured, and their log fO2 values were - 13.11 +/- 0.06 (Ni-NiO (NNO) + 0.7), - 13.05 +/- 0.06 (NNO + 0.8) and - 12.68 +/- 0.07 (NNO + 1.1), comparable with those reported previously. By placing an open capsule containing Ni powder below the sample capsule, the fO2 of the H2O pressure medium can be adjusted to reach that of the NNO buffer (NNO to NNO + 0.2). For the MnO-Mn3O4, Ni-NiO, and Co-CoO oxygen buffers, a steady-state fO2 was always achieved for each buffer at a fixed P-T condition. Measured log fO2 values for the Ni-NiO and Co-CoO buffers are in good agreement with theoretical values calculated from thermodynamic data and also with previous results obtained from vessels pressurized with Ar. The log fO2 values determined for the MnO-Mn3O4 buffer, about 0.3 log unit lower than the theoretical values, are consistent with previous values obtained from vessels pressurized with Ar. These results suggest that the use of H2O pressure medium would not perturb the equilibrium redox states of the oxygen buffers. In addition, we developed a miniature sensor that is small enough to be loaded together with other sample material, allowing the monitoring of fO2 in actual experiments. |
摘要_英文 |
Copyright © 中国科学院深海科学与工程研究所 备案证号:琼ICP备13001552号-1
琼公网安备 46020102000014号
地址: 三亚市鹿回头路28号 邮编:572000 网站维护:深海所办公室 邮箱:office@idsse.ac.cn